Petroleum Refining History

Year Process Process purpose Process by-products
1862Atmospheric distillationProduce keroseneNaphtha, tar, etc.
1870Vacuum distillationLubricants (original)Cracking feedstocks (1930s)Asphalt, residualCoker feedstocks
1913Thermal crackingIncrease gasolineResidual, bunker fuel
1916SweeteningReduce sulphur and odourSulphur
1930Thermal reformingImprove octane numberResidual
1932HydrogenationRemove sulphurSulphur
1932CokingProduce gasoline base stocksCoke
1933Solvent extractionImprove lubricant viscosity indexAromatics
1935Solvent dewaxingImprove pour pointWaxes
1935Catalytic polymerizationImprove gasoline yield and octane numberPetrochemical feedstocks
1937Catalytic crackingHigher octane gasolinePetrochemical feedstocks
1939VisbreakingReduce viscosityIncreased distillate, tar
1940AlkylationIncrease gasoline octane and yieldHigh-octane aviation gasoline
1940IsomerizationProduce alkylation feedstockNaphtha
1942Fluid catalytic crackingIncrease gasoline yield and octanePetrochemical feedstocks
1950DeasphaltingIncrease cracking feedstockAsphalt
1952Catalytic reformingConvert low-quality naphthaAromatics
1954HydrodesulphurizationRemove sulphurSulphur
1956Inhibitor sweeteningRemove mercaptanDisulphides
1957Catalytic isomerizationConvert to molecules with high octane numberAlkylation feedstocks
1960HydrocrackingImprove quality and reduce sulphurAlkylation feedstocks
1974Catalytic dewaxingImprove pour pointWax
1975Residual hydrocrackingIncrease gasoline yield from residualHeavy residuals